There are many leadership positions available to all students at Pascoe Vale Girls College. Students can participate in the leadership program from Years 7 to 12 in a variety of roles. Each of these positions have a specialized role within the school community, and with guidance from a mentor teacher, work within a small team who meet one lunchtime a week to plan and host events such as fundraisers, inter house competitions and other activities such a movie lunchtimes, photobooths, mindful colouring, sports tournaments, craft markets,Student leaders also participate in a Leadership Day every February where they plan events for the year, such as the International Women’s Day assemblies, with alumni speakers, and a lunchtime carnival.
- Diversity Captains who promote inclusivity and diversity within the school through programs and events such as Stand Out and IDAHOBIT Day.
- STEAM Captains who help coordinate science demonstrations for primary school visits, National Science Week and Science Club, as well as participate in the Rephract Telescope viewing evenings and other STEAM-related activities.
- Wellbeing Captains who work with the Wellbeing Team on programs and events that promote wellbeing within the school, for example, RU OK? Day.
- Sports Captains who assist with inter school sports competitions and lunchtime training.
- Library Captains who serve students at the circulation desk, shelve books, help make displays and host lunchtime activities in the Library.
- Values Captains who make, buy and price merchandise, stock and staff the House Token Shop.
- Art Club Captains who develop and lead creative projects for the school including Art Club activities, competitions and exhibitions.
- SRC Captains who run the Student Representative Council meetings, and initiate school improvement programs.
- Debating Captains who lead debating meetings to assist students with crafting and delivering their debates at inter school competitions, applying feedback from adjudicators.
- Lensation Club Captains who lead photography projects and events within the school community.
- St John Ambulance Captains who lead the St John Ambulance program through mentorship at their lunchtime meetings.
Alberti, Cowan, Melba and Wake House Captains who plan, organise and host student events at lunchtime.
- School Captains who represent PVGC at school and community events, design the yearbook and plan other senior events.
- Senior School and Middle School Captains who assist the coordinators with sub-school events, assemblies and other administrative tasks.